35 kg钛锰合金固态储氢系统的充放氢气过程 仿真与实验测试

Experimental Research on Solid-state Hydrogen Storage for Heavy Haul Transportation in Rail Transit

  • 摘要: 研究了基于钛锰合金的固态储氢系统性能。首先建立了储氢系统内部瞬态传热传质模型,模拟了充氢过程系统内部温度变 化;然后针对35kg储氢模块,研究分析了充氢和放氢过程中系统内部压力、氢气流量等变化,试验验证了所研制储氢模型 的充放氢性能。结果表明,随着充氢过程进行,充氢速率下降,前24kg氢气的充氢平均速率为9.32kg/h,35kg氢气的充氢 平均速率为7.65kg/h;放氢过程中,系统内部压力稳定性好,在80%以上的放氢量内,可保证10kg/h以上的放氢速度,放 氢压力维持在0.8MPa以上,可直接供给车载燃料电池使用。

     

    Abstract: applications and based on rail transit vehicle requirements, the performance of a solid-state hydrogen storage system based on Ti-Mn alloy is investigated. First of all,a transient heat and mass transfer model in the hydrogen storage system was developed,through which the internal temperature changes during hydrogenating process was simulated. Then,the internal pressure and hydrogen flow rate during hydrogenating and dehydrogenating process of a 35kg hydrogen storage system were investigated. Meanwhile, the hydrogenating and dehydrogenating performances of the developed hydrogen storage equipment were verified. Retrieval results demonstrated that the hydrogenating rate slightly decreased but still can maintain high flow rate at the end of filling process. In the dehydrogenating process,the internal pressure maintained stability. The dehydrogenating rate maintained 10kg/h within more than 80% hydrogen capacity, and the outlet pressure maintained more than 0.8MPa. Hence,the outlet hydrogen can be directly applied for fuel cell.

     

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